Description Allyl glycidyl ether is a colorless liquid glycidyl ether with a pleasant odor. The compound is insoluble in water and is less dense than water, so it floats easily on water. Allyl glycidyl ether is mildly toxic if ingested or inhaled. It is not classified as a human carcinogen. allow
Allyl glycidyl ether is a colorless liquid glycidyl ether with a pleasant odor. The compound is insoluble in water and is less dense than water, so it floats easily on water. Allyl glycidyl ether is mildly toxic if ingested or inhaled. It is not classified as a human carcinogen.
Prepare
In a condensation reaction, epichlorohydrin and allyl alcohol are used to synthesize allyl glycidyl ether.
use
Allyl glycidyl ether is used in sealants and adhesives. It is also used in the production of polyethylene caprolactam.
chemical properties
colorless liquid
chemical properties
Allyl glycidyl ether is a stable, colorless, flammable liquid with a pleasant odor. It is incompatible with strong oxidizing agents, acids and bases. Peroxides may form on contact with air during storage.
chemical properties
Allyl glycidyl ether is a colorless liquid with a strong sweet smell
physical properties
A clear, colorless, watery, flammable liquid with a strong, pleasant odor. The odor threshold was reported to be 47 mg/m 3 (cited in Verschueren, 1983).
use
Stabilizer for resin intermediates, chlorides, vinyl resins, and rubber.
use
Allyl glycidyl ether is a monoglycidyl derivative used as a reactive epoxy diluent for epoxy resins. As an impurity, it is considered a sensitizer for plastics industry workers allergic to 3-glycidoxypropyltrimethoxysilane, an epoxy silane Compounds used as fixative additives in silicones and polyurethanes.
use
Reactive diluent in epoxy resin systems; stabilizer for chlorinated compounds; rubber manufacturing
definition
The length of time something exists.
production method
AGE is produced by the condensation of allyl alcohol and epichlorohydrin, followed by dehydrochlorination with caustic soda to form an epoxide ring.
general instructions
Colorless liquid with pleasant odor. Flash point 135°F. The density is slightly smaller than water and insoluble in water. So it floats on the water. Toxic if eaten, mildly toxic by inhalation and skin contact. Very irritating to skin and eyes. Used in the manufacture of other chemicals.
air and water reaction
Flammable. Insoluble in water.
reactive profile
Allyl glycidyl ether reacts violently with oxidizing agents. Peroxides can form. Easy to polymerize [Handling Chemicals Safely 1980. p.128].
adventure
Skin, eye and upper respiratory tract irritation and dermatitis. Suspected carcinogen.
health hazard
May cause toxic effects if inhaled or absorbed through the skin. Inhalation or contact with material may cause irritation or burns to skin and eyes. Fires can produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from firefighting or dilution water may cause contamination.
health hazard
Occupational workers exposed to allyl glycidyl ether will experience severe poisoning symptoms, including but not limited to eye irritation, redness, pain, blurred vision, deep burns to the skin, respiratory system; causing mucosal damage, dermatitis, burning sensation, shortness of breath, Headache, drowsiness, dullness, nausea, vomiting, pulmonary edema, and anesthesia may affect hematopoiesis and reproduction. Acute exposure may cause central nervous system depression. Primary target organs include the eyes, skin, respiratory system, blood, and reproductive system.
fire hazard
Highly flammable: Easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may reach source of ignition and flash back. Most vapors are heavier than air. They spread along the ground and collect in low or tight areas (sewers, basements, water tanks). There is a vapor explosion hazard indoors, outdoors or in sewers. Runoff into sewers may create a fire or explosion hazard. Container may explode if heated. Many liquids are lighter than water.
Contact allergens
Allyl glycidyl ether is a monoglycidyl derivative used as a reactive epoxy diluent for epoxy resins. As an impurity, it is considered a sensitizer for plastics industry workers allergic to 3-glycidoxypropyltrimethoxysilane, an epoxy silane compound, Used as a fixing additive in silicones and polyurethanes
Security overview
Confirmed to be an animal carcinogen. Poisonous if swallowed. Moderately toxic by inhalation and skin contact. Report mutation data. Severe irritation to skin and eyes. May cause central nervous system depression and pulmonary edema. Flammable liquid when exposed to heat or flame; can react with oxidizing substances. When extinguishing fire, please use foam, carbon dioxide, dry powder. When decomposed by heat, it releases acrid and irritating fumes. See also allyl compounds
potential contact
Used as a solvent and emulsifier; in the manufacture of epoxy resins, chlorinated compounds; and rubber.
Carcinogenicity
In a 2-year inhalation carcinogenicity study in Osborne Mendel rats and B6C3F1 mice (50 animals of each sex at each exposure level), the animals were exposed to 0, 5, or 10 ppm AGE concentrations for 6 hours per day, weekly 5 days. Although respiratory epithelial tumors were occasionally observed, NTP concluded that these data provided only equivocal evidence of carcinogenicity in male rats and female mice. No evidence is available to support carcinogenesis in female rats. Some evidence of carcinogenesis in male mice included respiratory epithelial adenomas in 3 mice, dysplasia in 4 mice, and focal basal cell hyperplasia of the respiratory epithelium in the nasal passages in 7 mice.
environmental fate
biology. Bridie et al. (1979) reported BOD and COD values of 0.06 and 1.99 g/g for filtered wastewater from biosanitary waste treatment plants. These values were determined using standard dilution methods at 20 °C for 5 d. The ThOD of allyl glycidyl ether is 2.11 g/g. Chemistry/Physics. Hydrolysis of the epoxide ring may form 1-allyloxy-2,3-dihydroxypropane (Perez and Osterman-Golkar, 2000).
storage
Allyl glycidyl ether should be stored in a cool, light-proof and fire-proof area, separated from strong oxidants, strong bases and strong acids.
May form explosive mixture with air. Contact with acids or bases may cause explosive polymerization. Contact with oxidizing agents or amines may cause fire and explosion.
waste disposal
The material is dissolved or mixed with a flammable solvent and burned in a chemical incinerator equipped with an afterburner and scrubber. All federal, state and local environmental regulations must be followed.
Precautions
Occupational workers should not be near open flames, sparks or smoking areas during use and/or handling of allyl glycidyl ether. When temperatures are above 48°C, use closed system ventilation and explosion-proof electrical equipment. Workers should wear protective gloves, protective clothing and avoid all contact.
Contact Information XINSU VIET NAM NEW MATERIALS CO., LTD Address: No. 24, Nguyen Viet Xuan Street, Ninh Xa Ward, Bac Ninh City, Bac Ninh Province, Vietnam Tel:0387.051.600 Email: Xinsuvietnam@gmail.com